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另Blingnail的指甲油，今日亦以電話和製作廠聯繫，
波麗膠及指甲油皆經過SGS國際認證，不含重金屬及可塑劑！
MSDS: 19-4015
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Material Safety Data Sheet
Section 1: Identification of the Substance/Preparation and of the Company/Undertaking
Product Name:
Gelish - Soak Off Gel Polish
Chemical Name:
N/A
MSDS Prepared By:
MSDS Initial Approval Date:
January 2010
Family:
Gelish Soak Off Gel Polish
Manufacture:
Hand & Nail Harmony
14509 Best Ave unit B Norwalk, Ca 90650
Product Use:
Emergency Phone Number:
(800) 535-5053
Product #: Multiple Gelish - Soak Off Gel Polish Colors
Information Contacts:
(562) 623-4203
Section 2: Hazards Identification
● May be slightly toxic.
● May cause moderate skin injury (reddening & swelling).
● May cause eye irritation
Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry
No specific information available. Although, this product opposes only slight irritation concern with all routes of entry.
Eye
No specific information available. Contains materials that are essentially nonirritating, but contact may cause slight transient irritation
Skin
No specific information available. Contains materials that may cause moderate skin injury (reddening and swelling) and/or
sensitization. Prolonged contact may cause blister formation (burns). Since irritation may not occur immediately, contact can go
unnoticed.
Ingestion
No specific information available. Contains materials that may be practically nontoxic.
Inhalation
No specific information available. Low volatility makes vapor inhalation unlikely.
Sub-Chronic Effects
No specific information available. Limited tests showed no evidence of teratogenicity in animals. A lifetime skin painting study with
mice showed no evidence of carcinogenicity.
NOTE: Refer to Section II, Toxicological Information for Details
Section 3: Composition/Information on Ingredients
CAS#
EINECS#
INCI Name
Exposure OSHA TWA/STEL
Limits ACGIH TWA/STEL
%
41137-60-4
276-957-5
Di-Hema Trimethylhexyl Dicarbamate*
N/E
N/E
50-60
123-86-4
204-658-1
Butyl Acetate
N/E
N/E
10-13
141-78-6
205-500-4
Ethyl Acetate
N/E
N/E
9-12
868-77-9
212-782-2
HEMA
N/E
N/E
3-7
27813-02-1
248-666-3
Hydroxpropyl methacrylate
N/E
N/E
3-7
7534-94-3
231-403-1
Isobornyl Methacrylate
N/E
N/E
2-6
947-19-3
213-426-9
Hydroxycyclohexyl phenyl ketone
N/E
N/E
.2-.6
81-48-1
201-353-5
Violet 2/CI60725
N/E
N/E
0-1
9006-65-9
N/A
Dimethicone
N/E
N/E
77-92-9
201-069-1
Citric Acid
N/E
N/E
123-42-2
204-626-7
Diacetone Alcohol
N/E
N/E
12691-60-0
N/A
Stearalkonium Hectorite
N/E
N/E
7664-38-2
231-633-2
Phosphoric Acid
N/E
N/E
13463-67-7
236-675-5
Titanium Dioxide
N/E
N/E
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
2-Hydroxyethyl Methacrylate
Hydroxproply Methacrylate
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Ethyl Acetate
Not Listed
Not Listed
Burst 01338, Sea Foam 01341, Red Roses 01343, Desert Sand 01344, Moraccan Nights 01345, Tassels 01346,
Allure 01347, Bronzed 01355, Twinkle 01356, Vanilla Silk 01357, Taffeta 01359, Wicked 01360, Ivory Coast 01361,
Night Shimmer 01362, Good Gossip 01363, Ocean Wave 01364, Mint Icing 01365, Samuri 01366, Midnight Caller
01368, Rose Garden 01369
Hand & Nail Harmony GELISH-Ambience 01326, Basful 01328, Princess Tiara 01335, Rendevous 01336, Star
Butyl Acetate
Carcinogen IARC/NTP/OSHA
Chemical Identity
Di-Hema Trimethylhexyl Dicarbamate*
Not Listed
Not Listed
Diacetone Alcohol
Not Listed
Phosphoric Acid
Not Listed
Titanium Dioxide
Isobornyl Methacrylate
Hydroxcyclohexyl phenyl ketone
D&C Violet #2
Stearalkonium Hectorite
Not Listed
Color Formulations Could Contain Less than a total 1% in varying combinations of the following:
Dimeticone
Not Listed
Citric Acid
Not Listed
Page 1 of 5
12227-89-3
235-442-5
Black Iron Oxide
N/E
N/E
51274-00-1
257-098
Red Iron Oxide
N/E
N/E
5858-81-1
227-497-9
D&C Red #7
N/E
N/E
6417-83-0
229-142-3
D&C Red #34
N/E
N/E
* See section 16
Butyl Acetate
Ethyl Acetate
Section 4: First Aid Measures
First Aid for Eye
Flush with plenty of water for 15 minutes and retract eyelids often. Seek medical attention immediately.
First Aid for Skin
Remove contaminated clothing and wash contact area with soap and water for 15 minutes.
First Aid for Inhalation
In case of exposure to a high concentration of vapor or mist, remove person to fresh air. If breathing has stopped, administer
artificial respiration and seek medical attention.
First Aid for Ingestion
If appreciable quantities are swallowed, seek medical attention.
Section 5: Fire Fighting Measures
Method:
Extinguishing Media:
Use carbon dioxide or dry chemical for small fires; aqueous foam or water for large fires.
Fire Fighting Instructions:
Remove all ignition sources. Wear self-contained breathing apparatus and complete personal protective equipment when entering
confined areas where potential for exposure to vapors or products of combustion exists.
Unusual Hazards:
High temperatures and fire conditions may cause rapid and uncontrolled polymerization which can result in explosions and the
violent rupture of storage vessels or containers. Avoid the use of a stream of water to control fires since frothing can occur.
Section 6: Accidental Release Measures
Spill or Release Producers:
Spontaneous polymerization can occur. Eliminate ignition sources. Use eye and skin protection. Place leaking containers in a well
ventilated area. Dike and recover large spills. Soak up small spills with inert solids (such as vermiculite, clay) and sweep/shovel
into disposal container. Wash spill area with strong detregent and water solution; rinse with water, but minimize water use during
clean-up. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of
reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. EU Regulations
require the consultation of Directive 98/24/EC. Dispose and report per regulatory requirements if necessary. Please prevent
washings from entering waterways.
Section 7: Handling and Storage
Handling:
Avoid contact with skin and eyes. Avoid breathing vapor. Keep container closed when not in use. Avoid prolonged exposure to
light. Remove all contaminated clothing, shoes, belts and other leather goods immediately. Incinerate leather goods (including
shoes). Wash contaminated clothing thoroughly before reuse. Wash skin thoroughly with soap and water after handling. Solvents
should not be used to clean skin because of increased penetration potential.
Most acrylic monomers have low viscosities, thus only needing room temperature conditions to facilitate proper pouring techniques.
However, viscous type gels such as these may require heating to facilitate proper pouring techniques. To ensure that this happens
product may be heated to 60°C/140°F for not more than 24 hours. Do NOT use localized heat sources such as band heaters to
heat/melt product. Do NOT use steam. Hot boxes or hot rooms are recommended for heating/melting material. The hot box and/or
room should only be set to a maximum temperature of 60°C/140F. Do not overheat, this may compromise product effectiveness
and should be avoided. Refrain from multiple reheating of product, this will also diminishing the quality of the product.
Storage:
Product is extremely light sensitive. If exposed to natural light, LED, UVA, UVB or UV any light, material will cure very quickly.
Store in a cool, dry place, away from heat and all types of light. Store at temperatures below 100°F/38°C but above
the product's freezing point. If no freezing point is given, keep above 32°F/0°C at all times.
Explosion Hazard:
High temperatures and fire conditions may cause rapid and uncontrolled polymerization which can result in explosions and the
violent rupture of storage vessels or containers.
Section 8: Exposure Controls / Personal Protection
Engineering Controls
Local exhaust recommended to control exposure which may result from operations generating aerosols and hot operations
generating vapors.
No Data
Flammable Limit (vol%)
No Data
Flash Point ( °F/ °C)
Risk Phrases: R36//37/38, R43
Safety Phrases: S26, S36/37
Risk Phrases: R36/37/38
Auto-ignition Temperature (vol%)
Hazard Symbol: Xi
Hazard Symbol: Xi
Safety Phrases: S14, S3/7, S62
Risk Phrases: R36/37/38
Risk Phrases: R36/38, R43
Safety Phrases: S2, S26, S28
Safety Phrases: S26,S27,S28,S29,S30,S33,S35,S36
N/A - Not Applicable
Hazard Symbol: Xi
Hazard Symbol: Xi
N/E - None Established
N/R - Not Reviewed
N/DA - No Data Available
2-Hydroxy ethyl methacrylate:
Di-Hema Trimethylhexyl Dicarbamate
Isobomyl Methacrylate:
Hazard Symbol: Xi
Hazard Symbol: Xi
>212 °F/100 °C Seta flash
Hydroxypropyl Methacrylate:
See Section 16 for Risk and Safety Phrase Key
Risk Phrases: R36/38, R43
Risk Phrases: R36/38, R43
Safety Phrases: S2, S26
Safety Phrases: S2, S26
Not Listed
Red Iron Oxide
Not Listed
D&C Red #7
Not Listed
D&C Red #34
Not Listed
Black Iron Oxide
Page 2 of 5
Personal Protective Equipment
General:
To identify additional Personal protective Equipment (PPE) requirements, it is recommended that a hazard assessment in accordance
with the OSHA PPE Standard (29CFR1910.132), or European Standard EN166 be conducted before using this product. Provide eye
wash stations and safety showers. Wear impervious clothing to prevent ANY contact with this product, such as gloves, apron
boots, or whole body suits. Nitrile rubber is better than PVC.
Eye / Face Protection:
Wear chemical splash goggles
Skin Protection:
Wear impervious gloves (Neoprene)
Respiratory Protection:
A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain
limited circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by nuisance
level organic vapor dust masks can be used, however the use of the respirator is limited. Follow OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Section 9: Physical and Chemical Properties
pH
%Volatile
NA
By Volume: <0.5
Boiling Point/Freezing Point
Octanol/Water Partitioning Coefficient Log Po/w
Vapor Pressure:
Vapor Density
Evaporation Rate
Ignition
N/A
N/A
(mm Hg) @ 20 C:<0.01
No Data
No Data
No Data
Section 10: Stability and Reactivity
Stability
Incapability (Material to Avoid):
Normally Stable
Polymerization initiators including peroxides, strong oxidizing agents, copper, copper alloys, carbon steel, iron, rust
and strong bases.
Hazardous Decomposition Products:
Hazardous Polymerization:
Fumes produced when heated to
May occur --- Uncontrolled polymerization may cause rapid evolution of heat and increased pressure that could
decomposition may include:
result in violent rupture of sealed storage vessels or containers.
carbon monoxide, carbon dioxide
Conditions to Avoid:
Storage<100°F/38°C, exposure to light, loss of dissolved air, loss of polymerization, contamination with incompatible materials.
Section 11: Toxicological Information
Section 12: Ecological Information
Ecotoxicological Information
Chemical Fate Information
Section 13: Disposal Considerations
Non-contaminated, properly inhibited product is not a RCRA hazardous waste. It is the generators responsibility to determine what is classified as a hazardous waste.
Comply with all federal, state, and local regulations. Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual
vapors may explode on ignition; do not cut, drill, or weld on or near the container. Mix with compatible chemical which is less flammable and incinerate.
Section 14: Transport Information
DOT (49 CFR 172)
Proper Shipping Name:
Non-Regulated Material
Identification Number:
N/A
Marine Pollutant:
No
Special Provisions:
N/A
Emergency Response Guidebook (ERG) #:
N/A
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated.
Do not allow to enter drinking water supplies, wastewater, or soil.
N/DA
N/DA
N/DA
N/DA
Appearance
Clear to slight violet, viscous liquid
Odor & Odor Threshold
characteristic acrylate odor
Viscosity
Solubility In Water (20°C)
Decomposition Temperature
Specific Gravity
(H20=1): 1.15
N/DA
Insoluble
Flammable Limit (vol%)
Auto-ignition Temperature (vol%)
No Data
Acute Dermal Toxicity
No Data
Flash Point ( °F/ °C)
>212 °F/100 °C Seta flash
N/A
Acute Toxicity to Algae
Bioconcentration
Irritation - Eye
Acute Oral Toxicity
Acute Inhalation Toxicity
Irritation - skin
Sensitization
N/DA
Mutagenicity
N/DA
N/DA
Toxicity to Sewage Bacteria
No info available
Since this product contains a very low concentration of active components, the primary toxicological information is derived from the oligomers.
Chemical Oxygen Demand
No info available
Sub-chronic Toxicity
N/DA
No info available
Further hazardous properties cannot be excluded. The product should be handled with care when dealing with chemicals.
Biodegradability
N/DA
Acute Toxicity to Fish
Acute Toxicity to Invertebrates
N/DA
No info available
No info available
Page 3 of 5
IATA (DGR):
Proper Shipping Name:
Non-Regulated Material
Class or Division:
N/A
UN or ID Number:
N/A
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name:
Non-Regulated Material
Class or Division:
N/A
UN or ID Number:
N/A
Special Provisions & Stowage/Segregation:
None
Emergency Schedule (EmS)#:
Other Information:
Flash point >100 °C
Section 15: Regulatory Information
US Federal Regulations
Clean Air Act: HAP/ODS
This product contains the following hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act:
● NONE
This product contains no ODS's
Clean Water Act: Priority Pollutant
This product contains no chemicals listed under the U.S. Clean Water Act Priority Pollutant List
FDA: Food Packaging Status
This product has not been cleared by the FDA for use in food packaging and / or other applications as an indirect
food additive.
Occupational Safety and Health Act
This product is considered to be a hazardous chemical under the OSHA Hazard Communication Standard. Its hazard
are:
● Immediate (acute) health hazard
● Delayed (chronic) health hazard
● Reactive hazard
RCRA
This product is not considered to be a hazardous waste under RCRA (40 CFR 261)
SARA Title III: Section 302 (TPQ)
This product contains the following chemicals regulated under Sec. 302 as extremely hazardous substance that
carry a TPQ.
● NONE
SARA Title III: Section 304
This product contains the following chemicals regulated under Section 304 as extremely hazardous chemical for
emergency release notification ("CERCLA" List):
SARA Title III: Section 311-312:
This product is considered hazardous under the OSHA Hazard Communication Standard and is regulated under
Section 311-312 (40 CFR 370). Its hazards are:
● Immediate (acute) health hazard
● Delayed (chronic) health hazard
● Reactive hazard
SARA Title III: Section 313:
This product contains the following chemicals subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
TSCA Section 8(b) Inventory:
This product contains chemicals listed on the TSCA inventory or otherwise complies with TSCA premanufacture
notification requirements.
TSCA Significant New Use Rule:
None of the chemicals listed have a SNUR under TSCA.
State Regulations
CA Right-to-Know Law:
NONE
California No Significant Risk Rule:
NONE
MA Right-to-Know Law:
NONE
NJ Right-to-Know Law:
NONE
PA Right-to-Know Law:
NONE
FL Right-to-Know Law:
NONE
MN Right-to-Know Law:
NONE
International Regulations
CDSL: Canadian Inventory
Hydroxpropyl methacrylate CAS #27813-02-1 is on the DSL List. WHMIS = D2B
(on Canadian Transitional List)
Hyroxycyclohexyl phenyl ketone CAS# 947-19-3 is on the DSL list. WHMIS - n/da
2-Hydroxyethyl methacrylate CASE# 868-77-9 is on the DSL List. WHMIS - n/da
Isobornyl Methacrylate CAS# 7534-94-3 is on the DSL list. WHMIS - n/da
Labeling according to EC Directives - 1999/45/EC
European Community:
HNH Base Gel:
● HAZARD SYMBOLS: Xi irritant
● RISK PHRASES: R22: Harmful if swallowed, R36/38: Irritating to eyes and skin R43: May cause sensitization by
skin contact.
● SAFETY PHRASES: S18: Handle and open container with care, S24/25: avoid contact with skin and eyes, S36/37:
Wear suitable protective clothing and gloves, S38: in case of insufficient ventilation, wear suitable respiratory
equipment.
Page 4 of 5
Section 16: Other Information
EU Classes and Risk / Safety Phrases for Referenced Ingredients (See Section 2):
Hazard Symbols:
Xi - Irritants
Risk Phrases:
R36/37/38 Irritating to eyes, respiratory system and skin; R36/38 Irritating to eyes and skin; R43 May cause sensitization by skin contact
Safety Phrases:
S2 Keep out of reach of children; S3/7 Keep container tightly closed in a cool place; S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice; S27 Take off immediately all contaminated clothing; S28 After contact with skin, wash immediately with plenty of water; S29 Do not empty into drains;
S30 Never add water to this product; S33 Take precautionary measures against static discharges; S35 This material and its container must be disposed of in a safe way;
S36 Wear suitable protective clothing; S36/37 Wear suitable protective clothing and gloves S62 If swallowed, do not induce vomiting: seek medical advice immediately
and show the container or label.
Hazard Rating System (Pictograms)
NFPA:
HMIS:
Flammability (1)
Health (2)
Reactivity (1)
This information presented herein was obtained from sources considered to be reliable. However, this information is provided without any warranty, expressed or
implied, regarding its correctness or suitability for consumers intended use and/or application. For this and other reasons, we assume no responsibility and expressly
disclaim liability for loss, damage or expense arising out of any way connected with the handling, storage use or disposal of the product. This MSDS was prepared
expressly for this product. Use the materials only as directed. If the product is used as a component of another product, the information contained within the MSDS
may not be applicable. If there are any problems or concerns understanding this MSDS form, please direct all questions to INFOTRAC, Chemical Emergency Resources
System at (1-800-535-5053).
Page 5 of 5